Chemistry Letters

Synthesis, Structure, and Photochemistry of 2-Silyl-and 2-Disilanyl-2-aryl-1, 3-dithiane Derivatives.

AM Reddy, S Tsutsui, K Sakamoto

文献索引：Reddy, Anugula Mahipal; Tsutsui, Shinobu; Sakamoto, Kenkichi Chemistry Letters, 2001 , # 5 p. 476 - 477

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被引用次数: 1

摘要

A series of 2-silyl-and 2-disilanyl-substituted 2-aryl-1, 3-dithiane derivatives were prepared by the reactions of 2-aryl-2-lithio-1, 3-dithianes with the corresponding chlorosilanes. Photolysis of 2-phenyl-2-(pentamethyldisilanyl)-1, 3-dithiane resulted in the intermediary formation of 1, 1-dimethyl-2-phenyl-2-(trimethylsilyl)-1-silaethene.