A laser trapping-spectroscopy study on the photocyanation of perylene across a single micrometre-sized oil droplets/water interface: droplet-size effects on …
F Kitagawa, N Kitamura
文献索引：Kitagawa, Fumihiko; Kitamura, Noboru Physical Chemistry Chemical Physics, 2002 , vol. 4, # 18 p. 4495 - 4503
Photoirradiation of perylene in the presence of 1, 4-dicyanobenzene and NaCN in a benzonitrile (BN)/water emulsion under vigorous stirring gave 1-and 3-cyanoperylene in a total yield of 15%. For kinetic and mechanistic studies of the photoreaction, we conducted single-droplet measurements by using a laser trapping-microspectroscopy technique. Although determination of the incident light intensity absorbed by a solute in the emulsion ...
