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举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

The Journal of Organic Chemistry

Organotin nucleophiles. 5. Palladium-catalyzed allylic propargylation with allenylstannane

E Keinan, M Peretz

文献索引：Keinan, Ehud; Peretz, Moshe Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5302 - 5309

全文：HTML全文

被引用次数: 66

摘要

Allenyltrialkylstannanes were found to react with various allylic acetates in the presence of catalytic amounts of Pd (PPhd4 under mild neutral conditions, providing a novel approach for obtaining the 1, 5-enyne carbon skeleton. The regioselectivity of propargylation depends largely on the electron-withdrawing properties of the substituents at the two ends of the allylic system: substitution occurs at the end of closer proximity to the more electronegative ...

氰化钠结构式

乙酸酐结构式

3-(对甲苯基)丙烯醛结构式

3-(对甲苯基)丙烯醛

~%

[1-cyano-3-(4-methylphenyl)prop-2-enyl] acetate结构式

[1-cyano-3-(4-m...

beta-溴苯乙烯结构式

beta-溴苯乙烯

~%

acetic acid,1,5-diphenylpenta-1,4-dien-3-ol结构式

acetic acid,1,5...

肉桂醛结构式

~%

acetic acid,1,5-diphenylpenta-1,4-dien-3-ol结构式

acetic acid,1,5...

1,5-diphenylpenta-1,4-dien-3-ol结构式

1,5-diphenylpen...

乙酸酐结构式

~%

acetic acid,1,5-diphenylpenta-1,4-dien-3-ol结构式

acetic acid,1,5...

肉桂醛结构式

乙炔结构式

~%

1-苯基-1-戊烯-4-炔-3-醇结构式

1-苯基-1-戊烯-4-炔-3-醇

1-苯基-1-戊烯-4-炔-3-醇结构式

1-苯基-1-戊烯-4-炔-3-醇

~%

acetic acid,1-phenyl-5-trimethylsilylpent-1-en-4-yn-3-ol结构式

acetic acid,1-p...

肉桂醛结构式

~%

acetic acid,1-phenyl-5-trimethylsilylpent-1-en-4-yn-3-ol结构式

acetic acid,1-p...

三甲基氯硅烷结构式

三甲基氯硅烷

(E)-1-phenylpent-1-en-4-yn-3-yl acetate结构式

(E)-1-phenylpen...

~%

acetic acid,1-phenyl-5-trimethylsilylpent-1-en-4-yn-3-ol结构式

acetic acid,1-p...

1,2-丙二烯三正丁基锡结构式

1,2-丙二烯三正丁基锡

acetic acid,1-phenyl-5-trimethylsilylpent-1-en-4-yn-3-ol结构式

acetic acid,1-p...

~51%

trimethyl(5-phenylocta-3,6,7-trien-1-ynyl)silane结构式

trimethyl(5-phe...

trimethyl-[3-(2-phenylethenyl)hexa-1,5-diynyl]silane结构式

trimethyl-[3-(2...

详细

1,2-丙二烯三正丁基锡结构式

1,2-丙二烯三正丁基锡

acetic acid,1-phenyl-5-trimethylsilylpent-1-en-4-yn-3-ol结构式

acetic acid,1-p...

~6%

trimethyl(5-phenylocta-3,6,7-trien-1-ynyl)silane结构式

trimethyl(5-phe...

trimethyl-[3-(2-phenylethenyl)hexa-1,5-diynyl]silane结构式

trimethyl-[3-(2...

详细

1,2-丙二烯三正丁基锡结构式

1,2-丙二烯三正丁基锡

acetic acid,1-phenyl-5-trimethylsilylpent-1-en-4-yn-3-ol结构式

acetic acid,1-p...

~10%

trimethyl(5-phenylocta-3,6,7-trien-1-ynyl)silane结构式

trimethyl(5-phe...

trimethyl-[3-(2-phenylethenyl)hexa-1,5-diynyl]silane结构式

trimethyl-[3-(2...

详细

p-Chlorocinnamaldehyde结构式

p-Chlorocinnama...

氰化钠结构式

乙酸酐结构式

~%

[3-(4-chlorophenyl)-1-cyanoprop-2-enyl] acetate结构式

[3-(4-chlorophe...

乙酸(肉)桂酯结构式

乙酸(肉)桂酯

1,2-丙二烯三正丁基锡结构式

1,2-丙二烯三正丁基锡

~24%

[(E)-hex-1-en-5-ynyl]benzene结构式

[(E)-hex-1-en-5...

hexa-1,4,5-trienylbenzene结构式

hexa-1,4,5-trie...

1,2-丙二烯三正丁基锡结构式

1,2-丙二烯三正丁基锡

[1-cyano-3-(4-methylphenyl)prop-2-enyl] acetate结构式

[1-cyano-3-(4-m...

~33%

4-(4-methylphenyl)-3-butenenitrile结构式

4-(4-methylphen...

2-[2-(4-methylphenyl)ethenyl]pent-4-ynenitrile结构式

2-[2-(4-methylp...

[1-cyano-3-(4-methylphenyl)prop-2-enyl] acetate结构式

[1-cyano-3-(4-m...

~18%

4-(4-methylphenyl)-3-butenenitrile结构式

4-(4-methylphen...

2-[2-(4-methylphenyl)ethenyl]pent-4-ynenitrile结构式

2-[2-(4-methylp...

3-(对甲苯基)丙烯醛结构式

3-(对甲苯基)丙烯醛

~%

2-[2-(4-methylphenyl)ethenyl]pent-4-ynenitrile结构式

2-[2-(4-methylp...

trimethyl(prop-2-enyl)stannane结构式

trimethyl(prop-...

[1-cyano-3-(4-methylphenyl)prop-2-enyl] acetate结构式

[1-cyano-3-(4-m...

~18%

4-(4-methylphenyl)-3-butenenitrile结构式

4-(4-methylphen...

2-[2-(4-methylphenyl)ethenyl]pent-4-ynenitrile结构式

2-[2-(4-methylp...

trimethyl-[3-(2-phenylethenyl)hexa-1,5-diynyl]silane结构式

trimethyl-[3-(2...

~93%

3-ethynylhex-1-en-5-ynylbenzene结构式

3-ethynylhex-1-...

四烯丙基锡结构式

四烯丙基锡

acetic acid,1-phenylhex-1-en-4-yn-3-ol结构式

acetic acid,1-p...

~67%

3-prop-1-ynylhexa-1,5-dienylbenzene结构式

3-prop-1-ynylhe...

4-phenylnona-1,5-dien-7-yne结构式

4-phenylnona-1,...

详细

4-甲氧基肉桂醛结构式

4-甲氧基肉桂醛

三甲基氰硅烷结构式

三甲基氰硅烷

乙酸酐结构式

~%

[1-cyano-3-(4-methoxyphenyl)prop-2-enyl] acetate结构式

[1-cyano-3-(4-m...

[1-cyano-3-(4-methoxyphenyl)prop-2-enyl] acetate结构式

[1-cyano-3-(4-m...

~23%

4-(4-methoxyphenyl)but-3-enenitrile结构式

4-(4-methoxyphe...

2-[2-(4-methoxyphenyl)ethenyl]pent-4-ynenitrile结构式

2-[2-(4-methoxy...

4-甲氧基肉桂醛结构式

4-甲氧基肉桂醛

~%

2-[2-(4-methoxyphenyl)ethenyl]pent-4-ynenitrile结构式

2-[2-(4-methoxy...

1,2-丙二烯三正丁基锡结构式

1,2-丙二烯三正丁基锡

[1-cyano-3-(4-methoxyphenyl)prop-2-enyl] acetate结构式

[1-cyano-3-(4-m...

~23%

4-(4-methoxyphenyl)but-3-enenitrile结构式

4-(4-methoxyphe...

2-[2-(4-methoxyphenyl)ethenyl]pent-4-ynenitrile结构式

2-[2-(4-methoxy...

对氟苯甲醛结构式

对氟苯甲醛

~%

1-fluoro-4-(1-phenylhex-1-en-5-yn-3-yl)benzene结构式

1-fluoro-4-(1-p...

trans-1-(4-fluorophenyl)-3-phenylprop-2-en-1-ol结构式

trans-1-(4-fluo...

~%

1-fluoro-4-(1-phenylhex-1-en-5-yn-3-yl)benzene结构式

1-fluoro-4-(1-p...

苯乙酮结构式

~%

1-fluoro-4-(1-phenylhex-1-en-5-yn-3-yl)benzene结构式

1-fluoro-4-(1-p...

[1-cyano-3-(4-methoxyphenyl)prop-2-enyl] acetate结构式

[1-cyano-3-(4-m...

~23%

4-(4-methoxyphenyl)but-3-enenitrile结构式

4-(4-methoxyphe...

2-[2-(4-methoxyphenyl)ethenyl]pent-4-ynenitrile结构式

2-[2-(4-methoxy...

4-甲氧基肉桂醛结构式

4-甲氧基肉桂醛

~%

4-(4-methoxyphenyl)but-3-enenitrile结构式

4-(4-methoxyphe...

1,2-丙二烯三正丁基锡结构式

1,2-丙二烯三正丁基锡

[1-cyano-3-(4-methoxyphenyl)prop-2-enyl] acetate结构式

[1-cyano-3-(4-m...

~22%

4-(4-methoxyphenyl)but-3-enenitrile结构式

4-(4-methoxyphe...

2-[2-(4-methoxyphenyl)ethenyl]pent-4-ynenitrile结构式

2-[2-(4-methoxy...

[3-(4-chlorophenyl)-1-cyanoprop-2-enyl] acetate结构式

[3-(4-chlorophe...

~14%

4-(4-chlorophenyl)but-3-enenitrile结构式

4-(4-chlorophen...

2-[2-(4-chlorophenyl)ethenyl]pent-4-ynenitrile结构式

2-[2-(4-chlorop...

p-Chlorocinnamaldehyde结构式

p-Chlorocinnama...

~%

2-[2-(4-chlorophenyl)ethenyl]pent-4-ynenitrile结构式

2-[2-(4-chlorop...

1,2-丙二烯三正丁基锡结构式

1,2-丙二烯三正丁基锡

[3-(4-chlorophenyl)-1-cyanoprop-2-enyl] acetate结构式

[3-(4-chlorophe...

~15%

4-(4-chlorophenyl)but-3-enenitrile结构式

4-(4-chlorophen...

2-[2-(4-chlorophenyl)ethenyl]pent-4-ynenitrile结构式

2-[2-(4-chlorop...

对溴苯甲醛结构式

对溴苯甲醛

~%

1-bromo-4-(1-phenylhex-1-en-5-yn-3-yl)benzene结构式

1-bromo-4-(1-ph...

苯乙酮结构式

~%

1-bromo-4-(1-phenylhex-1-en-5-yn-3-yl)benzene结构式

1-bromo-4-(1-ph...

反式-4-硝基肉桂醛结构式

反式-4-硝基肉桂醛

氰化钠结构式

乙酸酐结构式

~%

[1-cyano-3-(4-nitrophenyl)prop-2-enyl] acetate结构式

[1-cyano-3-(4-n...

肉桂醛结构式

~%

acetic acid,1-phenylhex-1-en-4-yn-3-ol结构式

acetic acid,1-p...

(E)-1-phenyl-1-hexen-4-yn-3-ol结构式

(E)-1-phenyl-1-...

乙酸酐结构式

~%

acetic acid,1-phenylhex-1-en-4-yn-3-ol结构式

acetic acid,1-p...

1,2-丙二烯三正丁基锡结构式

1,2-丙二烯三正丁基锡

acetic acid,1-phenylhex-1-en-4-yn-3-ol结构式

acetic acid,1-p...

~%

3-prop-2-ynylhex-1-en-4-ynylbenzene结构式

3-prop-2-ynylhe...

4-phenylnona-1,7-diyn-5-ene结构式

4-phenylnona-1,...

详细

对甲基苯甲醛结构式

对甲基苯甲醛

~%

1-methyl-4-(1-phenylhex-1-en-5-yn-3-yl)benzene结构式

1-methyl-4-(1-p...

(E)-1-(4-methylphenyl)-3-phenyl-2-propen-1-ol结构式

(E)-1-(4-methyl...

~%

1-methyl-4-(1-phenylhex-1-en-5-yn-3-yl)benzene结构式

1-methyl-4-(1-p...

苯乙酮结构式

~%

1-methyl-4-(1-phenylhex-1-en-5-yn-3-yl)benzene结构式

1-methyl-4-(1-p...