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举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

Tetrahedron

Palladium-catalyzed intramolecular α-arylation of aliphatic ketone, formyl, and nitro groups

H Muratake, M Natsume, H Nakai

文献索引：Muratake, Hideaki; Natsume, Mitsutaka; Nakai, Hiroshi Tetrahedron, 2004 , vol. 60, # 51 p. 11783 - 11803

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被引用次数: 55

摘要

Intramolecular arylation of properly designed substrates bearing a ketone, formyl, or nitro terminating group was achieved by use of a PdCl2 (Ph3P) 2–Cs2CO3 reaction system to form a variety of carbocyclic compounds. Arylation in ketone compounds afforded benzene- annulated bridged or spirocycloalkanone derivatives, depending on the structure of the cyclization precursors. Arylation in formyl compounds occurred at the α-position (α- ...

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~83%

2-[2-(2-bromophenyl)ethyl]-2-chlorocyclohexan-1-one结构式

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1-bromo-2-(2-iodoethyl)benzene结构式

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2-[2-(2-bromophenyl)ethyl]-2-chlorocyclohexan-1-one结构式

2-[2-(2-bromoph...

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N-Cyclohexylcyclohexylideneamine结构式

N-Cyclohexylcyc...

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2-[2-(2-bromophenyl)ethyl]-2-chlorocyclohexan-1-one结构式

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N-Cyclohexylcyclohexylideneamine结构式

N-Cyclohexylcyc...

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2-[(2-bromophenyl)methyl]cyclohexan-1-one结构式

2-[(2-bromophen...

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邻溴溴苄结构式

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2-[(2-bromophenyl)methyl]cyclohexan-1-one结构式

2-[(2-bromophen...

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2-[2-(2-bromophenyl)ethyl]-2-chlorocyclohexan-1-one结构式

2-[2-(2-bromoph...

~74%

2-[2-(2-bromophenyl)ethyl]cyclohex-2-en-1-one结构式

2-[2-(2-bromoph...

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1-bromo-2-(2-iodoethyl)benzene结构式

1-bromo-2-(2-io...

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2-[2-(2-bromophenyl)ethyl]cyclohex-2-en-1-one结构式

2-[2-(2-bromoph...

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N-Cyclohexylcyclohexylideneamine结构式

N-Cyclohexylcyc...

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2-[2-(2-bromophenyl)ethyl]cyclohex-2-en-1-one结构式

2-[2-(2-bromoph...

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~%

2-[2-(2-bromophenyl)ethyl]cyclohex-2-en-1-one结构式

2-[2-(2-bromoph...

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N-Cyclohexylcyclohexylideneamine结构式

N-Cyclohexylcyc...

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2-(3-phenylpropyl)cyclohexan-1-one结构式

2-(3-phenylprop...

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1-bromo-2-(3-iodopropyl)benzene结构式

1-bromo-2-(3-io...

~%

2-(3-phenylpropyl)cyclohexan-1-one结构式

2-(3-phenylprop...

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1,2,3,4-Tetrahydro-1-nitronaphthalene结构式

1,2,3,4-Tetrahy...

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1-四氢萘酮结构式

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2-[2-(2-bromo-5-methoxyphenyl)ethyl]cyclohexanone结构式

2-[2-(2-bromo-5...

~81%

2-bromo-2-[2-(2-bromo-5-methoxyphenyl)ethyl]cyclohexan-1-one结构式

2-bromo-2-[2-(2...

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N-Cyclohexylcyclohexylideneamine结构式

N-Cyclohexylcyc...

~%

2-bromo-2-[2-(2-bromo-5-methoxyphenyl)ethyl]cyclohexan-1-one结构式

2-bromo-2-[2-(2...

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1-bromo-2-(2-iodoethyl)-4-methoxybenzene结构式

1-bromo-2-(2-io...

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2-bromo-2-[2-(2-bromo-5-methoxyphenyl)ethyl]cyclohexan-1-one结构式

2-bromo-2-[2-(2...

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2-[(2-bromophenyl)methyl]cyclopentan-1-one结构式

2-[(2-bromophen...

~18%

2-苄基环戊酮结构式

2-苄基环戊酮

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N-cyclohexylcyclopentanimine结构式

N-cyclohexylcyc...

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2-苄基环戊酮结构式

2-苄基环戊酮

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邻溴溴苄结构式

~%

2-苄基环戊酮结构式

2-苄基环戊酮

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2-[(2-bromophenyl)methyl]cyclopentan-1-one结构式

2-[(2-bromophen...

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2-苄基环戊酮结构式

2-苄基环戊酮

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1-(2-bromophenyl)prop-2-en-1-ol结构式

1-(2-bromopheny...

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1-(2-bromophenyl)-4-nitrobutan-1-one结构式

1-(2-bromopheny...

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2-溴苯甲醛结构式

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1-(2-bromophenyl)-4-nitrobutan-1-one结构式

1-(2-bromopheny...

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1-(2-bromophenyl)prop-2-en-1-ol结构式

1-(2-bromopheny...

~59%

1-(2-bromophenyl)prop-2-en-1-one结构式

1-(2-bromopheny...

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2-溴苯甲醛结构式

~%

1-(2-bromophenyl)prop-2-en-1-one结构式

1-(2-bromopheny...

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