Halomethyl metal compounds. XXXII. Insertion of phenyl (bromodichloromethyl) mercury-derived dichlorocarbene into carbon-hydrogen bonds. Alkanes and …

D Seyferth, JM Burlitch, K Yamamoto…

文献索引：Seyferth,D. et al. Journal of Organic Chemistry, 1970 , vol. 35, p. 1989 - 1993

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被引用次数: 23

摘要

76% 9% observed (eq 3).'0 A similar observation was made with vinylic silanes of the type A! te3SiCH= CHR. A mixture of cis-and trans-propenyltrimethylsilane gave only the expected C= C addition productsj9 as did a mixture of trans-R4eaSiCH= CHC4H9-n and Me3Si-(n- C4Hg) C= CHZ (eq 4). In contrast, the tertiary