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New domino sequences involving successive cleavage of carbon-carbon and carbon-oxygen bonds: Discrete product selection dictated by catalyst ligands

…, T Itahashi, H Amii, K Takahashi, Y Ito

文献索引:Murakami; Itahashi; Amii; Takahashi; Ito Journal of the American Chemical Society, 1998 , vol. 120, # 38 p. 9949 - 9950

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被引用次数: 57

摘要

Transition metal-mediated CC bond cleavage has received much attention in recent years. 1 Oxidative addition of a CC bond onto a transition metal provides a direct method to break a CC bond. 2 Catalytic reactions involving this elementary step, however, are still limited due to the inertness of CC σ-bonds toward transition metals. 3, 4 On the other hand, while common with alkali metal and alkali earth organometallics, CO bond cleavage by β- ...