Tetrahedron Letters

A convenient synthesis of 1, 1, 3, 4-tetramethylsilole: A stable IVB-metallole

A Laporterie, H Iloughmane, J Dubac

文献索引：Laporterie, Andre; Iloughmane, Hafida; Dubac, Jacques Tetrahedron Letters, 1983 , vol. 24, # 33 p. 3521 - 3522

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被引用次数: 21

摘要

Abstract 1, 1, 3, 4-tetramethyl-3-phenylcarbamoyl-1-silacyclopent-4-ene is found to undergo quantitative decomposition in refluxing CCl 4 to regiospecifically afford 1, 1, 3, 4- tetramethylsilole which is remarkably stable toward dimerisation, and is easily converted into its iron carbonyl-diene complex.