Catalysis today

Aerobic oxidation of secondary pyridine-derivative alcohols in the presence of carbon-supported noble metal catalysts

A Frassoldati, C Pinel, M Besson

文献索引：Frassoldati, Antonio; Pinel, Catherine; Besson, Michele Catalysis Today, 2013 , vol. 203, p. 133 - 138

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被引用次数: 7

摘要

Pt/C and PtBi/C catalysts prepared on a synthetic mesoporous carbon were evaluated in the oxidation of secondary aromatic alcohols (1-phenylethanol, α-methyl or phenyl pyridinemethanol) with air in different dioxane/water mixtures at 100° C under 10bar air. The observed activity for all substrates over both types of catalysts was strongly improved with the addition of water to the dioxane solvent as a result of different interactions of the ...