The Journal of Organic Chemistry

Acyl radicals: Intermolecular and intramolecular alkene addition reactions

DL Boger, RJ Mathvink

文献索引：Boger, Dale L.; Mathvink, Robert J. Journal of Organic Chemistry, 1992 , vol. 57, # 5 p. 1429 - 1443

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被引用次数: 180

摘要

1 2 80 C 3 dition products 3 were formed in high yields (53-74%) with little or no competitive acyl radical reduction (0-5%) 27 or decarbonylation (0%) in reactions that proved surprisingly independent of additional alkene substitution (Table I, entries 4-6). More important was the observation that the slow rate of aryl acyl radical reduction2'allowed the use of standard solution reaction conditions (method B: 1.3 equiv of Bu3SnH, 0.1 equiv of ...