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Photodimerization of coumarins in micelles: limitations of alignment effect

K Muthuramu, N Ramnath…

文献索引:Muthuramu, K.; Ramnath, N.; Ramamurthy, V. Journal of Organic Chemistry, 1983 , vol. 48, # 11 p. 1872 - 1876

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被引用次数: 43

摘要

Organized media such as micelles have shown great promise in achieving regio-and stereoselectivity in photochemical cycloaddition reactions as has been shown by recent reports. 7-Alkoxy-and 4-methyl-7-alkoxycoumarins dimerize in organic solvents to give the syn head-tail dimer. However, dimerization of these coumarins in SDS and CTAB micelles did not show any reversal in this trend. The results probably indicate that the micellar ...