Tetrahedron letters

Palladium-catalyzed phenyl-selenylation with n-Bu 3 SnSePh in one-pot two-step reactions

M Bonaterra, SE Martín, RA Rossi

文献索引：Bonaterra, Mariana; Martin, Sandra E.; Rossi, Roberto A. Tetrahedron Letters, 2006 , vol. 47, # 21 p. 3511 - 3515

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被引用次数: 39

摘要

We have studied the Pd-catalyzed cross-coupling reaction of a stannane derived from selenium n-Bu3SnSePh (1) with aryl and perfluoroalkyl iodides. Herein a very efficient one- pot two-step selenylation reaction to form a C–Se bond is reported. Ph2Se2 reacts with Na metal in liquid ammonia yielding PhSe− ions. To this solution n-Bu3SnCl was added to afford 1, which was introduced in the palladium-catalyzed coupling reaction without ...