Tetrahedron

A new fluorous/organic amphiphilic ether solvent, F-626: execution of fluorous and high temperature classical reactions with convenient biphase workup to separate …

H Matsubara, S Yasuda, H Sugiyama, I Ryu, Y Fujii…

文献索引：Matsubara, Hiroshi; Yasuda, Shinji; Sugiyama, Hiroyuki; Ryu, Ilhyong; Fujii, Yasuyuki; Kita, Katsumi Tetrahedron, 2002 , vol. 58, # 20 p. 4071 - 4076

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被引用次数: 42

摘要

A new fluorous/organic amphiphilic ether solvent, 1H, 1H, 2H, 2H-perfluorooctyl 1, 3- dimethylbutyl ether (F-626), is introduced. The basic properties of F-626, especially the partition coefficients with organic solvents/FC-72 (perfluorohexane), were investigated. F- 626 was easy to remove by fluorous biphase treatment. Using F-626 as a solvent, LAH reduction, catalytic hydrogenation, and fluorous reductive radical reactions were ...