Liebigs Annalen der Chemie

Conversion of oleic acid to 17??and 18??substituted stearic acid derivatives by way of the „acetylene zipper”

KE Augustin, HJ Schäfer

文献索引：Augustin, Kim E.; Schaefer, Hans J. Liebigs Annalen der Chemie, 1991 , # 10 p. 1037 - 1040

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被引用次数: 9

摘要

Abstract Stearolic acid (2) was prepared from oleic acid (1) and converted to 4, 5, and 7 by way of the „acetylene zipper” reaction. Compounds 5 and 7 were transformed to the (ω–1) ketones 8 and 9 and dimerized by way of the Glaser coupling reaction to 11 and 12. At daylight, 12 polymerizes to a blue polymer.