The Journal of Organic Chemistry

Simple enols. 3. Stereochemistry of simple enols in solution

B Capon, AK Siddhanta

文献索引：Capon, Brian; Siddhanta, Arup K. Journal of Organic Chemistry, 1984 , vol. 49, # 2 p. 255 - 257

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被引用次数: 27

摘要

The simple enols vinyl alcohol,(E)-prop-1-en-1-01,(2)-prop-1-en-1-01, and 2-methylprop-1- en-1-01 have been generated from reactive precursors in solution in slightly aqueous CD3COCD3 and their'H NMR spectra measured under conditions where exchange of the OH proton is slow on the NMR time scale. At-80 OC J (0H-C, H) for vinyl alcohol and (E)- prop-1-en-1-01 is greater than 9 Hz whereas that for (2)-prop-1-en-1-01 and 2-methylprop ...