Journal of the American Chemical Society

Silicon-induced fragmentations: stereoselective preparation of (Z, E)-and (Z, Z)-1, 4-dienamine derivatives. Synthesis of (9Z, 12E)-tetradecadien-1-yl acetate, …

NV Bac, Y Langlois

文献索引：Bac, N. V.; Langlois, Y. Journal of the American Chemical Society, 1982 , vol. 104, # 26 p. 7666 - 7667

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被引用次数: 25

摘要

Scheme I1 polyolefinic acetates, alcohols, or aldehydes, attracted increasing attenti~ n.~,~ Highly stereoselective methods were developed for the synthesis of these chemical messengers which are often active as a mixture of components in accurate proportions. Our approach to the synthesis of conjugated dienes using 2-alkylpyridines as starting material gave access to various Z, E, E, E, 4 and E, Z5 pheromones.