Elemental fluorine. Part 4. Use of elemental fluorine for the halogenation of aromatics

RD Chambers, CJ Skinner, MJ Atherton…

文献索引：Chambers, Richard D.; Skinner, Christopher J.; Atherton, Malcolm; Moilliet, John S. Journal of the Chemical Society, Chemical Communications, 1995 , # 1 p. 19 - 20

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被引用次数: 3

摘要

New methodolgy for direct iodination of benzenoid compounds has been developed; the aromatic substrate is simply mixed with iodine and sulfuric acid, suspended in an inert medium, such as 1, 1, 2-trichlorotrifluoroethane (CF2CICFCl2) or perfluorocarbon, and elemental fluorine is passed through the system at room temperature. High conversions to iodoaromatic products occur, even with some deactivated systems, eg nitrobenzene. A ...