A probable mechanism for the unexpected formation of N-acetylphenylalanine in the hydrogenolysis reaction is shown in Scheme I. The key to this mechanism is the formation of the oxazolidine 2-a generally accepted common intermediate for the 0 s N acyl migration in the acylated amino alcohol system. 8 The reduction of this cyclic intermediate 2 leads to the observed acyl shift hydrogenolysis product le. 9 The two minor components, ...
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![triethyl-[(1-methoxy-4-methyl-6-bicyclo[4.1.0]hept-3-enyl)oxy]silane结构式](https://image.chemsrc.com/caspic/452/88780-29-4.png)
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![triethyl-[(1-methoxy-6-bicyclo[4.1.0]hept-3-enyl)oxy]silane结构式](https://image.chemsrc.com/caspic/490/88780-28-3.png)
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