Oxymethylation of trifluoromethanesulfonamide with paraformaldehyde in ethyl acetate

…, A Kelling, U Schilde, IA Ushakov, BA Shainyan

文献索引：Meshcheryakov; Moskalik; Kelling; Schilde; Ushakov; Shainyan Russian Journal of Organic Chemistry, 2008 , vol. 44, # 2 p. 311 - 316

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被引用次数: 3

摘要

Abstract Acid-catalyzed reaction of trifluoromethanesulfonamide with paraformaldehyde in ethyl acetate led to the formation of oxymethylated products that did not form in the reaction carried out in sulfuric acid. Following products were obtained: 5-trifluoromethylsulfonyl-1, 3- dioxazinane, 3, 7-bis-(trifluoromethylsulfonyl)-1, 5, 3, 7-dioxadiazocane, and a complex of trifluoromethanesulfonamide with 2, 4, 8, 10-tetraoxospiro [5, 5] undecene, 1: 1. The ...