Chemistry Letters

AN ALTERNATIVE ROUTE TO PERALKYLCYCLOPOLYSILANES: THE REACTION OF 1, 2-DICHLOROTETRAALKYLDISILANES WITH LITHIUM

H Watanabe, J Inose, K Fukushima, Y Kougo…

文献索引：Watanabe, Hamao; Inose, Jun; Fukushima, Koji; Kougo, Yuichi; Nagai, Yoichiro Chemistry Letters, 1983 , p. 1711 - 1714

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被引用次数: 0

摘要

The reaction of 1, 2-dichlorotetraalkyldisilanes, Cl (R 1 R 2 Si) 2 Cl (R 1= R 2= i Pr; R 1, R 2= i Pr, Me; R 1, R 2= Me 3 SiCH 2, Me; R 1, R 2= t BuCH 2, Me; R 1, R 2= t Bu, Me), with an excess amount of lithium in tetrahydrofuran gave the corresponding peralkylcyclopolysilanes,[R 1 R 2 Si] n (n= 4–5), under mild conditions.