Organometallics

Silver-catalyzed silacyclopropenation of 1-heteroatom-substituted alkynes and subsequent rearrangement reactions

TB Clark, KA Woerpel

文献索引：Kosack, Steffen; Himbert, Gerhard Chemische Berichte, 1987 , vol. 120, p. 71 - 78

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被引用次数: 12

摘要

... Volume: Page ... Silylene transfer from silacyclopropane 1 to 1-bromo-1-hexyne 4 led to silylene insertion into the carbon−bromine bond to form bromosilane 5 (Figure 1; eq 2). Attempted silacyclopropenation of ethynyl p-tolyl sulfone (6) resulted in the formation of ...