Tetrahedron

Palladium (II)-catalyzed tandem annulation reaction of o-alkynylbenzoates with methyl vinyl ketone for the synthesis of isocoumarins

H Wang, X Han, X Lu

文献索引：Wang, Huan; Han, Xiuling; Lu, Xiyan Tetrahedron, 2013 , vol. 69, # 40 p. 8626 - 8631

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被引用次数: 10

摘要

Abstract A palladium (II)-catalyzed highly regioselective tandem reactions of o- alkynylbenzoates with methyl vinyl ketone for the synthesis of isocoumarins was developed. It is a convenient, mild and environmentally benign reaction with moderate to high yield. The reaction is initiated by the Pd (II) species and regenerate the Pd (II) species to complete the catalytic cycle without the necessity of a redox system.