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举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

o-Phenylene-bridged Cp/sulfonamido titanium complexes for ethylene/1-octene copolymerization

DJ Joe, CJ Wu, T Bok, EJ Lee, CH Lee, WS Han…

文献索引：Joe, Dae June; Wu, Chun Ji; Bok, Taekki; Lee, Eun Jung; Lee, Choong Hoon; Han, Won-Sik; Kang, Sang Ook; Lee, Bun Yeoul Dalton Transactions, 2006 , # 33 p. 4056 - 4062

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被引用次数: 7

摘要

The Suzuki-coupling reaction of 2-(dihydroxyboryl)-3, 4-dimethyl-2-cyclopenten-1-one (1) and 2-(dihydroxyboryl)-3-methyl-2-cyclopenten-1-one (2) with 2-bromoaniline derivatives affords cyclopentenone compounds (3–8) from which cyclopentadiene compounds, 4, 6-R′ 2-2-(2, 5-Me2C5H3) C6H2NH2 (9–11) and 4, 6-R′ 2-2-(2, 3, 5-Me3C5H2) C6H2NH2 (12– 14) are prepared. After sulfonation of the–NH2 group with p-TsCl, metallation is carried ...

(2,3-dimethyl-5-oxocyclopenten-1-yl)boronic acid结构式

(2,3-dimethyl-5...

2-溴苯胺结构式

~85%

2-(2-aminophenyl)-3,4-dimethylcyclopent-2-en-1-one结构式

2-(2-aminopheny...

(2,3-dimethyl-5-oxocyclopenten-1-yl)boronic acid结构式

(2,3-dimethyl-5...

2-溴-4,6-二甲基苯胺结构式

2-溴-4,6-二甲基苯胺

~73%

2-(2-amino-3,5-dimethylphenyl)-3,4-dimethylcyclopent-2-en-1-one结构式

2-(2-amino-3,5-...

(2,3-dimethyl-5-oxocyclopenten-1-yl)boronic acid结构式

(2,3-dimethyl-5...

2-溴-4,6-二氟苯胺结构式

2-溴-4,6-二氟苯胺

~78%

2-(2-amino-3,5-difluorophenyl)-3,4-dimethylcyclopent-2-en-1-one结构式

2-(2-amino-3,5-...

2-(2-aminophenyl)-3-methylcyclopent-2-en-1-one结构式

2-(2-aminopheny...

甲基锂结构式

~62%

2-(2,5-dimethylcyclopenta-1,4-dien-1-yl)aniline结构式

2-(2,5-dimethyl...

(2-methyl-5-oxocyclopenten-1-yl)boronic acid结构式

(2-methyl-5-oxo...

~%

2-(2,5-dimethylcyclopenta-1,4-dien-1-yl)aniline结构式

2-(2,5-dimethyl...

9-bromo-8-methyl-1,4-dioxaspiro[4.4]non-8-ene结构式

9-bromo-8-methy...

~%

2-(2,5-dimethylcyclopenta-1,4-dien-1-yl)aniline结构式

2-(2,5-dimethyl...

未登录结构式

甲基锂结构式

~69%

2-(2,5-dimethylcyclopenta-1,4-dien-1-yl)-4,6-dimethylaniline结构式

2-(2,5-dimethyl...

(2-methyl-5-oxocyclopenten-1-yl)boronic acid结构式

(2-methyl-5-oxo...

~%

2-(2,5-dimethylcyclopenta-1,4-dien-1-yl)-4,6-dimethylaniline结构式

2-(2,5-dimethyl...

2-溴-4,6-二甲基苯胺结构式

2-溴-4,6-二甲基苯胺

~%

2-(2,5-dimethylcyclopenta-1,4-dien-1-yl)-4,6-dimethylaniline结构式

2-(2,5-dimethyl...

9-bromo-8-methyl-1,4-dioxaspiro[4.4]non-8-ene结构式

9-bromo-8-methy...

~%

2-(2,5-dimethylcyclopenta-1,4-dien-1-yl)-4,6-dimethylaniline结构式

2-(2,5-dimethyl...

2-(2-aminophenyl)-3,4-dimethylcyclopent-2-en-1-one结构式

2-(2-aminopheny...

甲基锂结构式

~89%

2-(2,4,5-trimethylcyclopenta-1,4-dien-1-yl)aniline结构式

2-(2,4,5-trimet...

(2,3-dimethyl-5-oxocyclopenten-1-yl)boronic acid结构式

(2,3-dimethyl-5...

~%

2-(2,4,5-trimethylcyclopenta-1,4-dien-1-yl)aniline结构式

2-(2,4,5-trimet...

2-溴苯胺结构式

~%

2-(2,4,5-trimethylcyclopenta-1,4-dien-1-yl)aniline结构式

2-(2,4,5-trimet...

2-(2-amino-3,5-dimethylphenyl)-3,4-dimethylcyclopent-2-en-1-one结构式

2-(2-amino-3,5-...

甲基锂结构式

~75%

2,4-dimethyl-6-(2,4,5-trimethylcyclopenta-1,4-dien-1-yl)aniline结构式

2,4-dimethyl-6-...

(2,3-dimethyl-5-oxocyclopenten-1-yl)boronic acid结构式

(2,3-dimethyl-5...

~%

2,4-dimethyl-6-(2,4,5-trimethylcyclopenta-1,4-dien-1-yl)aniline结构式

2,4-dimethyl-6-...

2-溴-4,6-二甲基苯胺结构式

2-溴-4,6-二甲基苯胺

~%

2,4-dimethyl-6-(2,4,5-trimethylcyclopenta-1,4-dien-1-yl)aniline结构式

2,4-dimethyl-6-...

9-bromo-8-methyl-1,4-dioxaspiro[4.4]non-8-ene结构式

9-bromo-8-methy...

~94%

(2-methyl-5-oxocyclopenten-1-yl)boronic acid结构式

(2-methyl-5-oxo...

9-bromo-8-methyl-1,4-dioxaspiro[4.4]non-8-ene结构式

9-bromo-8-methy...

~%

2-(2-aminophenyl)-3-methylcyclopent-2-en-1-one结构式

2-(2-aminopheny...