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The Journal of Organic Chemistry

Synthesis, properties, and base-catalyzed interactions of 8-substituted 6, 7-dimethyllumazines

RL Beach, GWE Plaut

文献索引:Beach,R.L.; Plaut,G.W.E. Journal of Organic Chemistry, 1971 , vol. 36, # 25 p. 3937 - 3943

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被引用次数: 28

摘要

Alkaline solutions of 6, 7-dimethyllumazines substituted at position 8 with groups bearing a 2'-hydroxyl group exhibit no long wavelength absorption; analogs without a 2'-hydroxyl group show absorption in the visible range. In HtO, at alkaline pH, analogs with a 2'-hydroxyl substituent show nmr absorption of the 7-methyl group at-1.37 ppm, while the &methyl group exhibits singlets at-2.17 and-2.07 ppm. Analogs lacking the 2'-hydroxyl group do not ...