Chemistry–A European Journal

Synthetic applications in radical/radical cationic cascade reactions

H Rinderhagen, J Mattay

文献索引：Rinderhagen, Heiko; Mattay, Jochen Chemistry - A European Journal, 2004 , vol. 10, # 4 p. 851 - 874

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被引用次数: 31

摘要

Abstract Oxidative photoinduced electron transfer (PET) reactions have been performed with various cyclic cyclopropyl (vinyl) silyl ethers bearing an olefinic or acetylenic side chain. The reactions result in bi-to tetracyclic ring systems via a fragmentation–radical/radical cationic addition reaction pathway with well defined ring juncture. The mode of cyclisation (endo/exo) can be partially controlled by addition of nucleophiles due to the suppression ...