Electrochemistry of Organic Cations. VI. Investigations about the Cathodic Cleavage of Some Pyridinium and Triazolium Ions

…, A Henrion, W Abraham, G Michael

文献索引：Pragst, F.; Henrion, A.; Abraham, W.; Michael, G. Journal fuer Praktische Chemie (Leipzig), 1987 , vol. 329, # 6 p. 1071 - 1086

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被引用次数: 4

摘要

Abstract The electrochemical reduction of some N-acylamino-, N-amino-, N-benzyl-and N- phenacyl-substituted pyridinium and triazolium ions is investigated in acetonitrile by voltammetric methods and potentiostatic electrolyses. The acylaminopyridinium ions 1 and the arylaminopyridinium ions 3 are cathodically cleaved into the pyridine derivative and the carboxylic amide or the aromatic amine. In the case of the 1-benzyl-4-acylaminotriazolium ...