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European Journal of Organic Chemistry

A Formal Total Synthesis of (±)??1, 13??Herbertenediol

A Srikrishna, MS Rao

文献索引:Srikrishna, Adusuhilli; Rao, M. Srinivasa European Journal of Organic Chemistry, 2004 , # 3 p. 499 - 503

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被引用次数: 6

摘要

The sesquiterpenes cuparanes and herbertanes are interesting synthetic targets owing to the presence of a sterically crowded 1-aryl-1,2,2-trimethylcyclopentane moiety, and the difficulty associated with the construction of vicinal quaternary carbon atoms on a cyclopentane ring. The significant biological properties of the phenolic herbertanes make them important synthetic targets of current interest.3 Since its isolation, there are two reports on the synthesis of 1,13- ...