Journal of Fluorine Chemistry

Synthetic and mechanistic aspects of halo-F-methylphosphonates

RM Flynn, DJ Burton

文献索引：Flynn, Richard M.; Burton, Donald J. Journal of Fluorine Chemistry, 2011 , vol. 132, # 10 p. 815 - 828

被引用次数: 3

摘要

The synthesis of a variety of new halo-F-methylphosphonates has been achieved by a Michaelis–Arbuzov type reaction between a halo-F-methane and a trialkyl phosphite. This synthesis has proved to be of wide scope and utility for the high yield preparation of a number of heretofore unknown compounds. The 1H, 19F, 13C and 31P NMR spectroscopic properties are reported in detail. The mechanism for the formation of ...

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详细

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Synthetic and mechanistic aspects of halo-F-methylphosphonat...

[Journal of Fluorine Chemistry, , vol. 132, # 10 p. 815 - 828]