1-(Arylthio) cyclopropanecarboxaldehydes. Conjunctive reagents for secoalkylation

BM Trost, LN Jungheim

文献索引：Trost,B.M.; Jungheim,L.N. Journal of the American Chemical Society, 1980 , vol. 102, p. 7910

全文：HTML全文

被引用次数: 73

摘要

Abstract: The aldol products from 1-(arylthio) cyclopropanecarboxaldehydes and ketones undergo dehydration and addition of nucleophiles to the carbonyl group. The products are vinylogues of cyclopropylcarbinol systems that have previously been rearranged to cyclobutanones. The key for the successful rearrangement here is the employment of 2, 6- dimethoxyphenyl as the aryl group. The generated vinylcyclobutanones add a range of ...