Chemistry–A European Journal

Regioselective Silver??Mediated Kondakov–Darzens Olefin Acylation

NT Barczak, ER Jarvo

文献索引：Barczak, Nicholas T.; Jarvo, Elizabeth R. Chemistry - A European Journal, 2011 , vol. 17, # 46 p. 12912 - 12916

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被引用次数: 7

摘要

The Kondakov–Darzens acylation reaction dates back over a century and provides a robust method for the preparation of enones.[1] It is distinguished from the more common Friedel– Crafts acylation by the substitution of arenes with olefinic nucleophiles.[2] The most commonly employed reagents for this transformation are superstoichiometric quantities of polyphosphoric acid or highly Lewis acidic metal salts such as ...