Synthesis and photochemistry of heterocyclic norbornenyl ketones

…, SD Van Arnum, RP Gomez, RV Moquin

文献索引：Sauers, R. R.; Hagedorn, A. A.; Arnum, S. D. Van; Gomez, R. P.; Moquin, R. V. Journal of Organic Chemistry, 1987 , vol. 52, # 25 p. 5501 - 5505

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被引用次数: 16

摘要

A series of endo-5norbornenyl ketones 1 was prepared which contained the following heterocyclic rings: 2-fury1, 2-thienyl, N-methyl-2-pyrryl, 3, 5-dimethyl-4-isoxaolyl, 5-methyl-3- isoxazolyl and 2, 5-dimethyl-4-oxazolyl groups. Oxetanes 2 were produced from the ketones either by direct irradiation (A> 300 nm) or by use of photosensitizers. The two isoxazolyl systems were irradiated at 254 nm and found to lead to additional products, two of which ...