Basic-alkyl Esters of p-(Aminoalkyl)-benzoic Acids. I

FF Blicke, WM Lilienfeld

文献索引：Blicke; Lilienfeld Journal of the American Chemical Society, 1943 , vol. 65, p. 2281,2283

全文：HTML全文

被引用次数: 22

摘要

p-(Aminomethyl)-benzoic Acid.-p-Tolunitrile16(200 g.) was hydrolyzed with a mixture of 280 g. of sodium hydroxide, 1500 cc. of water and 300 cc. of alcohol, and the p-toluic acid (223 g., SGOjoO) obtained was heated with 150 K. of thionyl chloride; the g-loluyl chloride (282 g., 92% i boiled at 117-120'(24 mm.). 16 A brisk stream of dry chlorine was passed into 262 g. of p-toluyl chloride, heated to 120-130, for four hours while the material was illuminated ...