Planar and Nonplanar Unsaturation. Preparation, Properties and Molecular??Orbital Characterization of Some Fluoro??Derivatives of Anthracene and Anthraquinone
AY Meyer, A Goldblum
文献索引:Meyer,A.Y.; Goldblum,A. Israel Journal of Chemistry, 1973 , vol. 11, p. 791 - 804
Abstract Several fluoroanthracenes (I-III) and fluoroanthraquinones (IV-VII) were prepared, and their PMR and UV spectra, as well as dipole moments, recorded. These are discussed in terms of molecular-orbital data, both of the pi-electronic type (including nonbonding 2p- orbitals) and of the all-valence-electron type. PMR signals can be assigned on the basis of such calculations. The interpretation of UV spectra is straightforward in the case of ...