Novel radical reaction of phenylsulfonyl oxime ethers. A free radical acylation approach

S Kim, IY Lee, JY Yoon, DH Oh

文献索引：Kim, Sunggak; Lee, Ill Young; Yoon, Joo-Yong; Oh, Dong Hyun Journal of the American Chemical Society, 1996 , vol. 118, # 21 p. 5138 - 5139

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被引用次数: 113

摘要

Although acylation represents one of the most useful and thoroughly studied reactions in organic chemistry, 1 a successful free radical-mediated acylation is not presently available. Only a few examples, involving highly activated carbonyls such as biacetyl2 and acyl aldoximes, 3 have appeared to date. 4 It is also noteworthy that free radical carbonylation has recently been reported. 5 This reaction allows the introdution of carbonyl groups to ...