Canadian Journal of Chemistry

Electrophilic Additions to Ethylidenenorbornene and Vinylnorbornene

TC Shields

文献索引：Shields,T.C. Canadian Journal of Chemistry, 1971 , vol. 49, p. 1142 - 1146

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被引用次数: 6

摘要

Electrophilic and free radical additions to 5-ethylidenebicyclo [2.2. 1] hept-2-ene and 5- vinylbicyclo-[2.2. 1] hept-2-ene have been carried out with peracetic acid, hydrogen chloride, and methanol. In contrast to chlorosulfonyl isocyanate, peracetic acid primarily attacks the exocyclic double bond in 5-ethylidenebicyclo [2.2. 1] hept-2-ene. Several other electrophilic additions are discussed which demonstrate the unpredictable reactivity of the norbornyl ...