Novel synthesis of heterocycles using stannyl anion generated from Me3SiSnBu3 and F

M Mori, A Hashimoto, M Shibasaki

文献索引：Mori, Miwako; Hashimoto, Akira; Shibasaki, Masakatsu Journal of Organic Chemistry, 1993 , vol. 58, # 23 p. 6503 - 6504

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被引用次数: 19

摘要

It has been found that stannyl anion, which is generated from Me3SiSnBus in the presence of R4NX in DMF, can react with an aryl or vinyl halide to produce an aryl or vinyl anion.'The reaction procedure is very simple, and the aryl or vinyl anion generated can react intramolecularly with an aldehyde, ketone, or ester carbonyl group in a chain to give a cyclized product in good yield. During the course of our studies, we have found that F-is ...