Highly Selective 1, 4??and 1, 6??Addition of P (O) H Compounds to p??Quinones: A Divergent Method for the Synthesis of C??and O??Phosphoryl Hydroquinone …
B Xiong, R Shen, M Goto, SF Yin…
文献索引：Xiong, Biquan; Shen, Ruwei; Goto, Midori; Yin, Shuang-Feng; Han, Li-Biao Chemistry - A European Journal, 2012 , vol. 18, # 52 p. 16902 - 16910
Abstract The reaction of P (O)[BOND] H compounds with p-quinones could proceed through either 1, 4-or 1, 6-addition pathways by employing different additives to selectively give the corresponding C-and O-phosphoryl hydroquinone derivatives in good yields. Oxidative double 1, 4-addition of P (O)[BOND] H compounds to p-quinones was also achieved by tuning the solvent, affording a facile synthesis of bis-substituted hydroquinones with ...
