Electron transfer processes. 33. An inverted reactivity series in the reaction of tert-butyl radical with nucleophiles

GA Russell, RK Khanna

文献索引：Russell, Glen A.; Khanna, R. K. Journal of the American Chemical Society, 1985 , vol. 107, # 5 p. 1450 - 1452

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被引用次数: 18

摘要

Reactions were performed in nitrogen-purged Me2S0 in the presence of equimolar amounts of 18-crown-6, with irradiation from a 275-W sunlamp positioned ca. 15 cm from the Pyrex reaction flask.* Generated by the action of potassium tert-butoxide on the conjugate acid.'Yields determined by IH NMR and GLC on a I-mmol scale for reactions 0.1 M in RHgX N N-. dBased upon a series of experiments in Me2S0 at different N-and Me2C= N02- ...