Journal of organometallic chemistry

(Trifluoromethyl) germanes. Preparation and properties of (CF3) 2GeHX (X= H, D, F, Cl, Br, I, CH3) and CF3GeHnX3-n (X= H, D, CF2H, CH3)

R Eujen, R Mellies, E Petrauskas

文献索引：Eujen, R.; Mellies, R.; Petrauskas, E. Journal of Organometallic Chemistry, 1986 , vol. 299, p. 29 - 40

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被引用次数: 5

摘要

Abstract The hydrogenation of (CF 3) n GeX 4-n (X= halogen, n= 1–3) with NaBH 4 in an acidic medium has been investigated. Deuteration with NaBD 4 and D 3 PO 4 gave the partially deuterated species CF 3 GeH n D 3-n and (CF 3) 2 GeH n D 2-n in reasonable isotopic purity. The (CF 3) 2 GeHBr was isolated and converted into the halides (CF 3) 2 GeHX (X= F, Cl, I) by treatment with AgX or HX. Insertion of CF 2 into a Ge H bond has ...