Organic letters

Copper-catalyzed intermolecular hydroamination of alkenes

JG Taylor, N Whittall, KK Hii

文献索引：Taylor, Jason G.; Whittall, Neil; Hii, King Kuok Organic Letters, 2006 , vol. 8, # 16 p. 3561 - 3564

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被引用次数: 109

摘要

To the best of our knowledge, intermolecular hydroamination reactions catalyzed by copper complexes were only reported for reactions with alkenes containing electron- withdrawing substituents (Michael acceptors). 10 Following our recent discovery of copper(II) triflate as an effective catalyst for the addition of O−H bonds to norbornene, 11 we initiated a study to develop the corresponding hydroamination reactions. Herein, we provide the first examples of the copper-catalyzed ...