Tetrahedron letters

Moderate generation of sulfenylnitrenes from novel N-sulfenylsulfodiimides

T Yoshimura, T Fujie, T Fujii

文献索引：Yoshimura, Toshiaki; Fujie, Tetsuo; Fujii, Takayoshi Tetrahedron Letters, 2007 , vol. 48, # 3 p. 427 - 430

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被引用次数: 11

摘要

N-Sulfenylated sulfodiimides were first prepared by the reaction of S, S-diphenyl-N- tosylsulfodiimide with arenesulfenyl chlorides under the basic conditions. Thermolysis of S, S-diphenyl-N-(2-nitrophenylsulfenyl)-and S, S-diphenyl-N-(2, 4-dinitrophenylsulfenyl) sulfodiimides in the presence of olefins proceeded at 50–80° C to give the corresponding deiminated S, S-diphenyl-N-tosylsulfimide and N-sulfenylaziridines in very good yields. 2, ...