A novel silanediyl–germanediyl (silylene–germylene) exchange in 1, 1-dimethyl-2, 3, 4, 5-tetraphenyl-1-germacyclopentadiene

JA Hawari, D Griller

文献索引：Hawari, Jalal A.; Griller, David Journal of the Chemical Society, Chemical Communications, 1984 , # 17 p. 1160 - 1161

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被引用次数: 0

摘要

Photochemically generated dimethylsilanediyl reacts with 1 ,I -dimethyl-2,3,4,5-tetraphenyl-l -germacyclopentadiene to bring about a silanediyl-germanediyl exchange. ... The reactions of dimethylsilanediyl with cyclic dienes have been the subject of several investigations.14 For example, thermally generated dimethylsilanediyl reacts with cyclopent- adiene3 to cause ring expansion and the formation of products (1) and (2), reaction (1). Similarly, ...