Phytochemistry

Synthesis of (R)-and (S)-10, 16-dihydroxyhexadecanoic acid: cutin stereochemistry and fungal activation

…, T Crawford, S Gould, YS Ha, M Hollrah, F Noor-E-Ain…

文献索引：Ahmed, Aqeel; Crawford, Terry; Gould, Stephanie; Ha; Hollrah, Monica; Noor-E-Ain, Farhana; Dickman, Martin B.; Dussault, Patrick H. Phytochemistry, 2003 , vol. 63, # 1 p. 47 - 52

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被引用次数: 15

摘要

The first asymmetric syntheses of the cutin monomers (R)-and (S)-10, 16- dihydroxyhexadecanoic acid (10, 16-DHPA) and confirmation of (S)(+)-absolute configuration for 10, 16-DHPA derived from tomato are reported. The individual DHPA stereoisomers display differences in their ability to activate the fungal pathogen Colletotrichum trifolii.