前往化源商城

Journal of the American Chemical Society

The Alkaline Hydrolysis of Polynuclear Methyl Arylacetates

N Acton, E Berliner

文献索引:Acton,N.; Berliner,E. Journal of the American Chemical Society, 1964 , vol. 86, p. 3312 - 3318

全文:HTML全文

被引用次数: 20

摘要

Rates of the alkaline hydrolysis of 13 methyl arylacetates, XrCH2COOCH3, were determined in 85y0 aqueous methanol and/or in 76% aqueous acetone at four temperatures Esters in which the side chain is attached to a 1-naphthalene-like position react at considerably reduced rates, this is ascribed to steric hindrance to the approach of the reagent The rates of the unhindered compounds do not correlate well with various Huckel molecular orbital ...