Synthesis of dendritic iron (II) porphyrins with a tethered axial imidazole ligand designed as new model compounds for globins

P Weyermann, F Diederich

文献索引：Weyermann, Philipp; Diederich, Francois Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 24 p. 4231 - 4233

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被引用次数: 38

摘要

A series of novel dendritic iron (II) porphyrins with an axial imidazole ligand attached to the central porphyrin core was synthesised and fully characterised. The vacancy of the second axial coordination site was demonstrated by their ability to coordinate the diatomic gas molecules CO, O 2 and NO. The formation of NO complexes by dendritic iron (II) porphyrins was observed for the first time.