Organometallics

Synthetic, Structural, and Redox Studies of Arene Alkyl Complexes of Tantalum (III) Supported by Aryloxide and Arenethiolate Ligands

DSJ Arney, PA Fox, MA Bruck, DE Wigley

文献索引：Arney, David S. J.; Fox, Peter A.; Bruck, Michael A.; Wigley, David E. Organometallics, 1997 , vol. 16, # 15 p. 3421 - 3430

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被引用次数: 11

摘要

The arene complexes of tantalum (III)(η6-C6Me6) Ta (OAr) 2Cl (Ar= 2, 6-C6H3iPr2) and (η6- C6Me6) Ta (OAr) Cl2 have been alkylated and the new alkyl complexes compared to their halide analogues. For example,(η6-C6Me6) Ta (OAr) R2 (R= Me, Et, SiMe3, or Ph) complexes have been prepared and characterized by a variety of methods, including cyclic voltammetry studies.