The reaction of gem-dichloroallyllithium with halides of silicon, germanium, tin and mercury, and with triphenylborane. Equilibrium vs. kinetic control of regioselectivity
D Seyferth, GJ Murphy, RA Woodruff
文献索引：Seyferth,D. et al. Journal of Organometallic Chemistry, 1977 , vol. 141, p. 71 - 83
Abstract The reactions of gem-dichloroallyllithium, which was prepared by the low temperature reactions of n-butyllithium with 3, 3, 3-trichloropropene or with 3, 3- dichloroallyltriphenyllead, with trimethylchlorosilane, trimethylchlorogermane, trimethyltin bromide, mercuric chloride and iodomethane were examined. With trimethylchlorosilane and iodomethane, 1, l-dichloroallyl products were obtained exclusively and with ...
