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Boron photochemistry: IX. Synthesis and fluorescent properties of dimesityl-phenylboranes

JC Doty, B Babb, PJ Grisdale, M Glogowski…

文献索引:Doty,J.C. et al. Journal of Organometallic Chemistry, 1972 , vol. 38, p. 229 - 236

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被引用次数: 67

摘要

Abstract A series of p-substituted phenyldimesitylboranes has been synthesized by reaction of dimesitylboron fluoride with appropriately substituted phenyllithium derivatives. The quantum yields of fluorescence in cyclohexane vary with the nature of the p-substituent as follows: Br≈ Cl< CN< CH 3≈ H< N (CH 3) 2< N (C 6 H 5) 2.