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New synthesis of allylic sulfones and their conversion to polyolefins.. beta.-Carotene from vitamin A

G Buechi, RM Freidinger

文献索引:Buechi; Freidinger Journal of the American Chemical Society, 1974 , vol. 96, # 10 p. 3332 - 3333

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被引用次数: 47

摘要

R= HC 3 to the rearrangement of cinnamyl trichloromethanesulfenate to cinnamyl trichloromethyl sulfoxide8 and P-ionyl p-toluenesulfinate to P-ionyl p-tolyl sulfone. In these cases an allylic shift would have resulted in loss of conjugation and/or increased steric interactions. Carbon tetrachloride in the presence of potassium hydroxide lo at room temperature converted sulfones