Tetrahedron

Distinguishihg ionization from sulfur p-type lone pair orbitals and carbon π-molecular orbitals by he I/He II photoelectron spectroscopy

RS Glass, JL Broeker, ME Jatcko

文献索引：Glass, Richard S.; Broeker, Jeffrey L.; Jatcko, Mark E. Tetrahedron, 1989 , vol. 45, # 5 p. 1263 - 1272

全文：HTML全文

被引用次数: 26

摘要

He I and He II photoelectron spectra of methylthiomethylbenzene (2), 2-(1-nethylethylthio) ethylbenzene (3), 1-naphthalenemethanethiol (4), 1, 1-dimethylethylthiobenzene (5), benzenethiol (6), and methylthiobenzene (7) are reported. Comparison of the He I and He II band areas for each compound provide a reliable basis for assigning the bands as due to photoionization from a carbon π-molecular orbital, sulfur p-type lone pair orbital, or mixed ...