Synthesis of Unsymmetrical Ketones by Palladium-Catalyzed Cross-Coupling Reaction of Carboxylic Anhydrides with Organoboron Compounds.

…, S Yasumi, I Shimizu, A Yamamoto

文献索引：Kakino, Ryuki; Yasumi, Sayaka; Shimizu, Isao; Yamamoto, Akio Bulletin of the Chemical Society of Japan, 2002 , vol. 75, # 1 p. 137 - 148

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被引用次数: 102

摘要

On the basis of fundamental studies on oxidative addition of carboxylic anhydrides to zerovalent palladium complexes to yield acyl (carboxylato) bis (tertiary phosphine) palladium (II) complexes and their reactions with organoboronic acids to yield ketones, a novel catalytic process has been developed. This converts carboxylic anhydrides and organoboron compounds into ketones catalyzed by palladium complexes under mild ...